Grinding the Cubes?Multigram Solid-State Synthesis of Silsesquioxane Amic Acids
نویسندگان
چکیده
For the first time, ball milling is used in functionalization of silsesquioxanes. The solid-state nucleophilic addition aminopropylisobutyl POSS to cyclic anhydrides leads silsesquioxane amic acids virtually quantitative yields without use a solvent. reactions are easily scalable and can be adopted multigram quantities.
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ژورنال
عنوان ژورنال: ACS Sustainable Chemistry & Engineering
سال: 2021
ISSN: ['2168-0485']
DOI: https://doi.org/10.1021/acssuschemeng.1c05188